The rescue comes first and it is urgent, because it has a deadline the rest of the work does not: the person's last day. Their contacts, mail, and negotiation history get frozen safely while they are still reachable. A few thousand files and a few hundred contacts is a normal size. I do not try to organise it early. Organising it badly is worse than organising it late. Freeze it first; file it once we know what it is.
Then the build: the frozen material becomes plain files you own, on your own drive, that AI can read and answer questions from. The knowledge stops living in a head and starts living somewhere the whole team can reach.